Carbon Disulfide → HCID 178444348, compound

HRID 1111494Notes

Reaction equation

HRID 1111494 reaction equation
[CH:1](/[C@H:6]1[CH2:11][CH2:10][C@H:9]([C:12]2[CH:18]=[CH:17][C:15]([NH2:16])=[CH:14][CH:13]=2)[CH2:8][CH2:7]1)=[CH:2]\[CH2:3][CH2:4][CH3:5].[CH2:19]([N:21]([CH2:24][CH3:25])[CH2:22][CH3:23])[CH3:20].[C:26](=[S:28])=[S:27]>CCCCCC>[CH:1](/[C@H:6]1[CH2:7][CH2:8][C@H:9]([C:12]2[CH:13]=[CH:14][C:15]([NH:16][C:26](=[S:27])[S-:28])=[CH:17][CH:18]=2)[CH2:10][CH2:11]1)=[CH:2]\[CH2:3][CH2:4][CH3:5].[CH2:19]([NH+:21]([CH2:24][CH3:25])[CH2:22][CH3:23])[CH3:20]

Participants

5

Reactant 3

HCID 6348Carbon DisulfideHCID 8471TriethylamineHCID 178444345HCID 178444345, compound

Product 1

HCID 178444348HCID 178444348, compound

Reagents, catalysts & solvents 1

HCID 8058HexaneSolvent

Procedure

A solution of 390 mg of p-[trans-4-(trans-1-pentenyl)cyclohexyl]aniline (purity 93%) in 4 ml of hexane was treated successively with 446 μl of triethylamine and 214 μl of carbon disulphide and the mixture was then left to stand at 0° C. for 65 hours. The yellow precipitate obtained was filtered off, washed twice with hexane and dried in a high vacuum. There were obtained 428 mg of triethylammonium p-[trans 4-(trans-1-pentenyl)cyclohexyl]phenyldithiocarbamate which was processed directly without additional purification.

Workup

  1. waitthe mixture was then left
  2. customThe yellow precipitate obtained
  3. filtrationwas filtered off
  4. washwashed twice with hexane
  5. customdried in a high vacuum

Sources & evidence

ORD record
ord-8c6b14a90d3f4d65b95eb9e0aa985921
Source dataset
uspto-grants-1990_12
Patent number
US04980486

Reaction notes

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