Acrylamide → HCID 86736064, compound

HRID 1112075Notes

Reaction equation

HRID 1112075 reaction equation
[C:1]([NH2:5])(=[O:4])[CH:2]=[CH2:3].[C:6]([O:10][CH2:11][CH2:12][C:13]#[N:14])(=[O:9])[CH:7]=[CH2:8]>N(C(C)(C)C#N)=NC(C)(C)C#N.CN(C)C=O.CC(C)=O>[C:1]([NH2:5])(=[O:4])[CH:2]=[CH2:3].[C:6]([O:10][CH2:11][CH2:12][C:13]#[N:14])(=[O:9])[CH:7]=[CH2:8]

Participants

6

Reactant 2

HCID 6579AcrylamideHCID 78252-Cyanoethyl acrylate

Product 1

HCID 86736064HCID 86736064, compound

Reagents, catalysts & solvents 3

HCID 6547AzobisisobutyronitrileCatalystHCID 180AcetoneSolventHCID 6228DimethylformamideSolvent

Procedure

7.11 g of acrylamide, 3.13 g of β-cyanoethyl acrylate (commercially available from Monomer-Polymer, Borden Chemical Co., New York, New York, under the designation #7437) and 0.01 g of 2,2'-azobis-[2-methylpropionitrile] catalyst were dissolved in 80 ml of dimethylformamide. This solution was polymerized under N2 in a sealed tube at 65° C. for 12 hours. A white viscous solution resulted which produced a precipitate in acetone. The precipitate was collected and dried under vacuum at 50° C. for 12 hours to yield a water-soluble white powder.

Workup

  1. customThis solution was polymerized under N2 in a sealed tube at 65° C. for 12 hours
  2. customA white viscous solution resulted which
  3. customThe precipitate was collected
  4. customdried under vacuum at 50° C. for 12 hours
  5. customto yield a water-soluble white powder

Sources & evidence

ORD record
ord-3b91efb65e85458da4d3106a1a524660
Source dataset
uspto-grants-1978_10
Patent number
US04120727

Reaction notes

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