Hydrogen Peroxide → HCID 22765156, compound

HRID 1112130Notes

Reaction equation

HRID 1112130 reaction equation
[Cl:1][CH2:2][CH2:3][S:4]([CH2:7][CH2:8][C:9]([NH:11][CH2:12][CH2:13][S:14][CH:15]=[CH2:16])=[O:10])(=[O:6])=[O:5].[OH:17]O>C(O)(=O)C>[Cl:1][CH2:2][CH2:3][S:4]([CH2:7][CH2:8][C:9]([NH:11][CH2:12][CH2:13][S:14]([CH:15]=[CH2:16])=[O:17])=[O:10])(=[O:5])=[O:6]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 227651493-(2-Chloroethanesulfonyl)-N-[2-(ethenylsulfanyl)ethyl]propanamide

Product 1

HCID 22765156HCID 22765156, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent2×

Procedure

A suspension of 6 g Intermediate 2 in 25 ml acetic acid was treated at 20° C. with 2.5 ml of 30 % hydrogen peroxide and 3 ml acetic acid. After 2 hours the solution was evaporated and the residue stirred with ether. The solid was filtered, dried and recrystallised from ethanol-petrolether. Yield 4.85 g; Mp. 108° to 109° C.

Workup

  1. customAfter 2 hours the solution was evaporated
  2. filtrationThe solid was filtered
  3. customdried
  4. customrecrystallised from ethanol-petrolether

Sources & evidence

ORD record
ord-e459a77a6f2043d4b7b9f1eb0f6bbedb
Source dataset
uspto-grants-1978_10
Patent number
US04120898

Reaction notes

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