Hydrogen Peroxide → HCID 22765159, compound

HRID 1112132Notes

Reaction equation

HRID 1112132 reaction equation
[Cl:1][CH2:2][CH2:3][C:4]([NH:6][C:7]([NH:9][CH2:10][CH2:11][S:12][CH:13]=[CH2:14])=[O:8])=[O:5].[OH:15]O>C(O)(=O)C>[Cl:1][CH2:2][CH2:3][C:4]([NH:6][C:7]([NH:9][CH2:10][CH2:11][S:12]([CH:13]=[CH2:14])=[O:15])=[O:8])=[O:5]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 22765154HCID 22765154, compound

Product 1

HCID 22765159HCID 22765159, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

4.05 g Intermediate 6 in 20 ml acetic acid was oxidised with 30 % hydrogen peroxide in the usual way. After 2 hours, the solution was evaporated and the residue stirred with ether. The solidified product was filtered off and recrystallised from ethanolpetrolether. Yield 3.1 g; Mp. 113° to 135° C.

Workup

  1. customthe solution was evaporated
  2. filtrationThe solidified product was filtered off
  3. customrecrystallised from ethanolpetrolether

Sources & evidence

ORD record
ord-1b12998c522749f09485c9136719f997
Source dataset
uspto-grants-1978_10
Patent number
US04120898

Reaction notes

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