proline dl-form → HCID 59856833, compound

HRID 1114937Notes

Reaction equation

HRID 1114937 reaction equation
[C:45](=[O:46])([O-:47])[O-:48].[CH2:31]1[CH2:32][O:33][CH2:34][CH2:35][NH:36]1.[CH3:51][S:52]([CH3:53])=[O:54].[CH:1]([CH3:2])([CH3:3])[O:4][C:5](=[O:6])[N:7]1[CH2:8][CH2:9][CH:10]([O:13][c:14]2[n:15][cH:16][n:17][c:18]([NH:22][c:23]3[c:24]([F:30])[cH:25][c:26]([I:29])[cH:27][cH:28]3)[c:19]2[C:20]#[N:21])[CH2:11][CH2:12]1.[Cu:55][I:56].[K+:49].[K+:50].[OH:37][C:38]([CH:39]1[NH:40][CH2:41][CH2:42][CH2:43]1)=[O:44]>>[CH:1]([CH3:2])([CH3:3])[O:4][C:5](=[O:6])[N:7]1[CH2:8][CH2:9][CH:10]([O:13][c:14]2[n:15][cH:16][n:17][c:18]([NH:22][c:23]3[c:24]([F:30])[cH:25][c:26]([N:36]4[CH2:31][CH2:32][O:33][CH2:34][CH2:35]4)[cH:27][cH:28]3)[c:19]2[C:20]#[N:21])[CH2:11][CH2:12]1

Participants

8

Reactant 7

HCID 614proline dl-formHCID 679Dimethyl SulfoxideHCID 813Potassium Cation2×HCID 8083MorpholineHCID 19660Carbonate IonHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 67202884HCID 67202884, compound

Product 1

HCID 59856833HCID 59856833, compound

Sources & evidence

ORD record
ord-21102e48152d4be9bbc3bc22a75b62c7
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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