Dichloromethane → 3-Methanesulfonyl-5-triethoxyprop-1-ynyl-pyridine

HRID 1121368Notes

Reaction equation

HRID 1121368 reaction equation
[Br:1][c:2]1[cH:3][n:4][cH:5][c:6]([S:8](=[O:9])(=[O:10])[CH3:11])[cH:7]1.[CH2:12]([CH3:13])[O:14][C:15]([C:16]#[CH:17])([O:18][CH2:19][CH3:20])[O:21][CH2:22][CH3:23].[CH3:24][CH2:25][N:26]([CH2:27][CH3:28])[CH2:29][CH3:30].[Cl:33][CH2:34][Cl:35].[Cu:31][I:32]>>[c:2]1([C:17]#[C:16][C:15]([O:14][CH2:12][CH3:13])([O:18][CH2:19][CH3:20])[O:21][CH2:22][CH3:23])[cH:3][n:4][cH:5][c:6]([S:8](=[O:9])(=[O:10])[CH3:11])[cH:7]1

Participants

6

Reactant 5

HCID 6344DichloromethaneHCID 8471TriethylamineHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 109209723,3,3-Triethoxyprop-1-yneHCID 223919813-Bromo-5-(methylsulfonyl)pyridine

Product 1

HCID 225703163-Methanesulfonyl-5-triethoxyprop-1-ynyl-pyridine

Sources & evidence

ORD record
ord-065ccf0b50d44c6ba1b0a235d3cb4b5a
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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