proline dl-form → HCID 57831046, compound

HRID 1122382Notes

Reaction equation

HRID 1122382 reaction equation
[Br:1][c:2]1[n:3][c:4]2[c:5]([n:6][cH:7]1)[n:8]([CH2:17][O:18][CH2:19][CH2:20][Si:21]([CH3:22])([CH3:23])[CH3:24])[cH:9][c:10]2[C:11]([C:12]([CH3:13])([CH3:14])[CH3:15])=[O:16].[C:25](=[O:26])([O-:27])[O-:28].[CH3:46][S:47]([CH3:48])=[O:49].[Cu:50][I:51].[K+:29].[K+:30].[NH2:39][c:40]1[cH:41][cH:42][cH:43][cH:44][cH:45]1.[OH:31][C:32]([CH:33]1[NH:34][CH2:35][CH2:36][CH2:37]1)=[O:38]>>[c:2]1([NH:39][c:40]2[cH:41][cH:42][cH:43][cH:44][cH:45]2)[n:3][c:4]2[c:5]([n:6][cH:7]1)[n:8]([CH2:17][O:18][CH2:19][CH2:20][Si:21]([CH3:22])([CH3:23])[CH3:24])[cH:9][c:10]2[C:11]([C:12]([CH3:13])([CH3:14])[CH3:15])=[O:16]

Participants

8

Reactant 7

HCID 614proline dl-formHCID 679Dimethyl SulfoxideHCID 813Potassium Cation2×HCID 6115AnilineHCID 19660Carbonate IonHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 578292211-(2-bromo-5-((2-(trimethylsilyl)ethoxy)methyl)-5H-pyrrolo[2,3-b]pyrazine-7-yl)-2,2-dimethylpropane-1-one

Product 1

HCID 57831046HCID 57831046, compound

Sources & evidence

ORD record
ord-7097bc0786a34ea8b9da36f09856422f
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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