Acetate → Methyl 2-diphenylphosphino-1-naphthoate

HRID 1122435Notes

Reaction equation

HRID 1122435 reaction equation
[C:46]([O-:47])(=[O:48])[CH3:49].[C:51]([O-:52])(=[O:53])[CH3:54].[CH3:23][CH2:24][N:25]([CH2:26][CH3:27])[CH2:28][CH3:29].[CH3:43][C:44]#[N:45].[F:1][C:2]([F:3])([F:4])[S:5]([O:6][c:7]1[c:8]([C:17](=[O:18])[O:19][CH3:20])[c:9]2[cH:10][cH:11][cH:12][cH:13][c:14]2[cH:15][cH:16]1)(=[O:21])=[O:22].[Pd+2:50].[c:30]1([PH:36][c:37]2[cH:38][cH:39][cH:40][cH:41][cH:42]2)[cH:31][cH:32][cH:33][cH:34][cH:35]1>>[c:7]1([P:36]([c:30]2[cH:31][cH:32][cH:33][cH:34][cH:35]2)[c:37]2[cH:38][cH:39][cH:40][cH:41][cH:42]2)[c:8]([C:17](=[O:18])[O:19][CH3:20])[c:9]2[cH:10][cH:11][cH:12][cH:13][c:14]2[cH:15][cH:16]1

Participants

7

Reactant 6

HCID 175Acetate2×HCID 6342AcetonitrileHCID 8471TriethylamineHCID 70017DiphenylphosphineHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 11034997Methyl 2-trifluoromethanesulfonyloxy-1-naphthoate

Product 1

HCID 11760420Methyl 2-diphenylphosphino-1-naphthoate

Sources & evidence

ORD record
ord-d655f8f5f6e046d99c7f7596f2d045a7
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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