Sodium ion → 3-Iodo-6-(4-methoxyphenyl)-1,2,3,6,7,8,9,9a-octahydroquinolizin-4-one

HRID 1131646Notes

Reaction equation

HRID 1131646 reaction equation
[CH2:41]([Cl:42])[Cl:43].[CH3:25][N:26]([CH3:27])[CH2:28][CH2:29][N:30]([CH3:31])[CH3:32].[CH3:44][CH2:45][O:46][C:47](=[O:48])[CH3:49].[CH3:6][O:7][c:8]1[cH:9][cH:10][c:11]([CH:14]2[N:15]3[C:16](=[O:24])[CH2:17][CH2:18][CH2:19][CH:20]3[CH2:21][CH2:22][CH2:23]2)[cH:12][cH:13]1.[I:1][Si:2]([CH3:3])([CH3:4])[CH3:5].[I:33].[Na+:39].[Na+:40].[S:34]([O-:35])([O-:36])(=[O:37])=[S:38]>>[I:1][CH:17]1[C:16](=[O:24])[N:15]2[CH:14]([c:11]3[cH:10][cH:9][c:8]([O:7][CH3:6])[cH:13][cH:12]3)[CH2:23][CH2:22][CH2:21][CH:20]2[CH2:19][CH2:18]1

Participants

9

Reactant 8

HCID 923Sodium ion2×HCID 1084Thiosulfate ionHCID 6344DichloromethaneHCID 8037N,N,N',N'-TetramethylethylenediamineHCID 8857Ethyl AcetateHCID 24841Hydrogen iodideHCID 85247Trimethylsilyl iodideHCID 69070864HCID 69070864, compound

Product 1

HCID 690775263-Iodo-6-(4-methoxyphenyl)-1,2,3,6,7,8,9,9a-octahydroquinolizin-4-one

Sources & evidence

ORD record
ord-44fd198729ea451d95a0223ca6c2a7bf
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

Loading…