Dimethyl Sulfoxide → tert-Butyl 4-methoxy4-(1,3-dioxopent-1-yl)piperidine-1-carboxylate

HRID 1140464Notes

Reaction equation

HRID 1140464 reaction equation
[CH3:33][CH2:34][N:35]([CH2:36][CH3:37])[CH2:38][CH3:39].[CH3:7][S:8](=[O:9])[CH3:10].[Cl:1][C:2]([C:3]([Cl:4])=[O:5])=[O:6].[Cl:40][CH2:41][Cl:42].[OH:11][CH:12]([CH2:13][C:14](=[O:15])[C:16]1([O:29][CH3:30])[CH2:17][CH2:18][N:19]([C:22](=[O:23])[O:24][C:25]([CH3:26])([CH3:27])[CH3:28])[CH2:20][CH2:21]1)[CH2:31][CH3:32]>>[O:11]=[C:12]([CH2:13][C:14](=[O:15])[C:16]1([O:29][CH3:30])[CH2:17][CH2:18][N:19]([C:22](=[O:23])[O:24][C:25]([CH3:26])([CH3:27])[CH3:28])[CH2:20][CH2:21]1)[CH2:31][CH3:32]

Participants

6

Reactant 5

HCID 679Dimethyl SulfoxideHCID 6344DichloromethaneHCID 8471TriethylamineHCID 65578Oxalyl chlorideHCID 21984004tert-Butyl 4-(3-hydroxy-1-oxopent-1-yl)-4-methoxypiperidine-1-carboxylate

Product 1

HCID 21983976tert-Butyl 4-methoxy4-(1,3-dioxopent-1-yl)piperidine-1-carboxylate

Sources & evidence

ORD record
ord-6135f34dec214099945914d0e912333c
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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