Ammonium → 5-amino-3-(N-t-butoxycarbonyl-1,2,5,6-tetrahydropyrid-4-yl)-1H-indole

HRID 1145633Notes

Reaction equation

HRID 1145633 reaction equation
[Cl-:26].[Fe:28].[N+:1]([O-:2])(=[O:3])[c:4]1[cH:5][c:6]2[c:7]([C:13]3=[CH:14][CH2:15][N:16]([C:19](=[O:20])[O:21][C:22]([CH3:23])([CH3:24])[CH3:25])[CH2:17][CH2:18]3)[cH:8][nH:9][c:10]2[cH:11][cH:12]1.[NH4+:27]>>[NH2:1][c:4]1[cH:5][c:6]2[c:7]([C:13]3=[CH:14][CH2:15][N:16]([C:19](=[O:20])[O:21][C:22]([CH3:23])([CH3:24])[CH3:25])[CH2:17][CH2:18]3)[cH:8][nH:9][c:10]2[cH:11][cH:12]1

Participants

5

Reactant 4

HCID 223AmmoniumHCID 312ChlorideHCID 23925IronHCID 54262828tert-Butyl 4-(5-nitro-1H-indol-3-yl)-5,6-dihydropyridine-1(2H)-carboxylate

Product 1

HCID 543263845-amino-3-(N-t-butoxycarbonyl-1,2,5,6-tetrahydropyrid-4-yl)-1H-indole

Sources & evidence

ORD record
ord-a822dcac1de6486f972de288d91d9518
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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