Acetate → HCID 178447503, compound

HRID 1152618Notes

Reaction equation

HRID 1152618 reaction equation
[Br:1][c:2]1[c:3]2[c:4]([O:11][CH:12]3[CH:13]([O:14][C:15]([C:16]([CH3:17])([CH3:18])[CH3:19])=[O:20])[CH:21]([O:22][C:23]([C:24]([CH3:25])([CH3:26])[CH3:27])=[O:28])[CH:29]([O:30][C:31]([C:32]([CH3:33])([CH3:34])[CH3:35])=[O:36])[CH:37]([CH2:39][O:40][C:41]([C:42]([CH3:43])([CH3:44])[CH3:45])=[O:46])[O:38]3)[n:5][nH:6][c:7]2[cH:8][cH:9][cH:10]1.[CH2:47]=[CH:48][c:49]1[cH:50][cH:51][cH:52][cH:53][cH:54]1.[CH3:55][CH2:56][N:57]([CH2:58][CH3:59])[CH2:60][CH3:61].[CH3:62][c:63]1[cH:64][cH:65][cH:66][cH:67][c:68]1[P:69]([c:70]1[cH:71][cH:72][cH:73][cH:74][c:75]1[CH3:76])[c:77]1[cH:78][cH:79][cH:80][cH:81][c:82]1[CH3:83].[CH3:84][C:85]#[N:86].[O-:88][C:89]([CH3:90])=[O:91].[O-:92][C:93]([CH3:94])=[O:95].[Pd+2:87]>>[c:2]1([CH:47]=[CH:48][c:49]2[cH:50][cH:51][cH:52][cH:53][cH:54]2)[c:3]2[c:4]([O:11][CH:12]3[CH:13]([O:14][C:15]([C:16]([CH3:17])([CH3:18])[CH3:19])=[O:20])[CH:21]([O:22][C:23]([C:24]([CH3:25])([CH3:26])[CH3:27])=[O:28])[CH:29]([O:30][C:31]([C:32]([CH3:33])([CH3:34])[CH3:35])=[O:36])[CH:37]([CH2:39][O:40][C:41]([C:42]([CH3:43])([CH3:44])[CH3:45])=[O:46])[O:38]3)[n:5][nH:6][c:7]2[cH:8][cH:9][cH:10]1

Participants

8

Reactant 7

HCID 175Acetate2×HCID 6342AcetonitrileHCID 7501StyreneHCID 8471TriethylamineHCID 80271Tri-o-tolylphosphineHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 178447502HCID 178447502, compound

Product 1

HCID 178447503HCID 178447503, compound

Sources & evidence

ORD record
ord-e6ec61c1ace2433187c3425f1a63d26a
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (7/10)

Reaction notes

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