Hydrochloric Acid → HCID 20535077, compound

HRID 1156584Notes

Reaction equation

HRID 1156584 reaction equation
[NH2:1][C:2]1[N:3]([SH:9])[N:4]=[N:5][C:6]=1[NH:7][NH2:8].[C:10]([CH:13]1[CH2:18][CH2:17][CH2:16][CH2:15][C:14]1=O)(=O)[CH3:11].Cl>C(O)C>[NH2:1][CH:2]1[C:6]([N:7]2[C:14]3[CH2:15][CH2:16][CH2:17][CH2:18][C:13]=3[C:10]([CH3:11])=[N:8]2)=[N:5][NH:4][N:3]1[SH:9]

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 134002-AcetylcyclohexanoneHCID 12960442HCID 12960442, compound

Product 1

HCID 20535077HCID 20535077, compoundYield 9.5%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

4-Amino-5-hydrazino-3-mercapto-1,2,3-triazole (7.3 g, 0.05 mol), 7.0 g (0.05 mol) acetyl cyclohexanone, 1.25 ml concentrated hydrochloric acid, and 350 ml ethanol are refluxed for 3 hours, evaporated to dryness, and recrystallized from ethyl acetate to give 1.2 g of white crystals, m.p. 201°-2°.

Workup

  1. customevaporated to dryness
  2. customrecrystallized from ethyl acetate

Sources & evidence

ORD record
ord-2edbb1fe40f8497a99b74becf493fc76
Source dataset
uspto-grants-1982_06
Patent number
US04336375

Reaction notes

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