Nickel → Nickel bis(2-ethylhexanoate)

HRID 1156729Notes

Reaction equation

HRID 1156729 reaction equation
[Ni:1].[CH2:2]([CH:4]([CH2:8][CH2:9][CH2:10][CH3:11])[C:5]([OH:7])=[O:6])[CH3:3].[N+]([O-])([O-])=O.[NH4+].C([O-])(=O)C.[NH4+]>O>[CH2:2]([CH:4]([CH2:8][CH2:9][CH2:10][CH3:11])[C:5]([O-:7])=[O:6])[CH3:3].[Ni+2:1].[CH2:2]([CH:4]([CH2:8][CH2:9][CH2:10][CH3:11])[C:5]([O-:7])=[O:6])[CH3:3]

Participants

6

Reactant 4

HCID 935NickelHCID 86972-Ethylhexanoic AcidHCID 22985Ammonium nitrateHCID 517165Ammonium Acetate

Product 1

HCID 107553Nickel bis(2-ethylhexanoate)

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Conditions

Temperature
85 °C

Procedure

A mixture of 50 grams (0.852 mole) of powdered nickel (particle size 3 to 7 microns), 248 grams (1.710 moles) of 2-ethylhexanoic acid (acid number, 387), a catalyst solution prepared by dissolving 10 grams of ammonium nitrate and 5 grams of ammonium acetate in 30 grams of water, and 170 grams of mineral spirits was agitated and heated to 85° C. The reaction mixture was maintained at 80°-85° C. for 6 hours while it was sparged with air at the rate of 30 liters per hour. It was then heated to 135° C. under vacuum to remove water from it. After the reaction product had been filtered and diluted with mineral spirits, there was obtained a solution of nickel 2-ethylhexanoate in mineral spirits that contained l0% by weight of nickel and had an acid number of 21.7.

Workup

  1. customa catalyst solution prepared
  2. temperatureThe reaction mixture was maintained at 80°-85° C. for 6 hours while it
  3. customwas sparged with air at the rate of 30 liters per hour
  4. temperatureIt was then heated to 135° C. under vacuum
  5. customto remove water from it
  6. filtrationAfter the reaction product had been filtered
  7. additiondiluted with mineral spirits

Sources & evidence

ORD record
ord-37de6a68e94d4a2e81749aa78599e6cf
Source dataset
uspto-grants-1982_06
Patent number
US04337208

Reaction notes

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