Ethyl formate → HCID 20534431, compound

HRID 1156981Notes

Reaction equation

HRID 1156981 reaction equation
[CH3:1][O:2][C:3]1[CH:4]=[C:5]([C:9]2([CH2:16][C:17]([O:19][CH2:20][CH3:21])=[O:18])[CH2:14][CH2:13][CH2:12][CH2:11][C:10]2=[O:15])[CH:6]=[CH:7][CH:8]=1.[CH:22](OCC)=[O:23].[Na]>>[CH3:1][O:2][C:3]1[CH:4]=[C:5]([C:9]2([CH2:16][C:17]([O:19][CH2:20][CH3:21])=[O:18])[CH2:14][CH2:13][CH2:12][CH:11]([CH:22]=[O:23])[C:10]2=[O:15])[CH:6]=[CH:7][CH:8]=1

Participants

4

Reactant 3

HCID 8025Ethyl formateHCID 5360545SodiumHCID 12838404HCID 12838404, compound

Product 1

HCID 20534431HCID 20534431, compound

Procedure

Following the procedure set forth in Example 1, 2-(3-methoxyphenyl)-2-ethoxycarbonylmethylcyclohexanone was reacted with ethyl formate in the presence of metallic sodium to provide 2-(3-methoxyphenyl)-2-ethoxycarbonylmethyl-6-formylcyclohexanone.

Sources & evidence

ORD record
ord-06b3a49288b44cf2815fd3d7962d07f1
Source dataset
uspto-grants-1982_06
Patent number
US04337341

Reaction notes

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