Allyl iodide → HCID 13023238, compound

HRID 1156993Notes

Reaction equation

HRID 1156993 reaction equation
[OH:1][C:2]1[CH:3]=[C:4]([C:8]23[CH2:16][CH2:15][CH2:14][CH:13]2[CH2:12][NH:11][CH2:10][CH2:9]3)[CH:5]=[CH:6][CH:7]=1.[CH2:17](I)[CH:18]=[CH2:19].C(=O)(O)[O-].[Na+]>>[OH:1][C:2]1[CH:3]=[C:4]([C:8]23[CH2:16][CH2:15][CH2:14][CH:13]2[CH2:12][N:11]([CH2:19][CH:18]=[CH2:17])[CH2:10][CH2:9]3)[CH:5]=[CH:6][CH:7]=1

Participants

4

Reactant 3

HCID 11166Allyl iodideHCID 516892Sodium BicarbonateHCID 13023229HCID 13023229, compound

Product 1

HCID 13023238HCID 13023238, compound

Procedure

Following the procedure set forth in Example 36, 4a-(3-hydroxyphenyl)-2,3,4,4a,5,6,7,7a-octahydro-1H-2-pyrindine was reacted with allyl iodide in the presence of sodium bicarbonate to provide 4a-(3-hydroxyphenyl)-2-(2-propenyl)-2,3,4,4a,5,6,7,7a-octahydro-1H-2-pyrindine. M.P. 106°-108° C.

Sources & evidence

ORD record
ord-580531529a51457d9987a49574f8eb1e
Source dataset
uspto-grants-1982_06
Patent number
US04337341

Reaction notes

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