HRID1164574

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID971

Oxalic acid

C2H2O4

HCID61373

Oxalic acid dihydrate

C2H6O6

结构：CC(=O)[O-].CC[P+](c1ccccc1)(c1ccccc1)c1ccccc1

HCID94470

Ethyltriphenylphosphonium acetate

C22H23O2P

PRODUCTS

生成物

结构：CC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.CC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.O=C([O-])C(=O)[O-]

HCID20037189

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID887

Methanol

CH4O

2 次

PROCEDURE

实验过程

To a 2 gallon bottle was charged 1000 g (1.707 mol) of a 70% methanol solution of ethyltriphenylphosphonium acetate.acetic acid complex followed by the addition of 204.4 g (1.622 mol) of oxalic acid dihydrate. The mixture was mixed until all the oxalic acid had dissolved and then about 31.5 g of methanol was added to give a resultant solution of about 50 wt. % ethyltriphenylphosphonium oxalate.

WORKUP

后处理

dissolutionhad dissolved

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-6f5673f3b3b14a148c291e99f53885f7
来源数据集: uspto-grants-1983_01
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04370465
来源说明: uspto-grants-1983_01

反应 SMILES

C([O-])(=O)C.[CH2:5]([P+:7]([C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1)([C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1)[C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)[CH3:6].O.O.[C:28]([OH:33])(=[O:32])[C:29]([OH:31])=[O:30].C(O)(=O)C(O)=O>CO>[C:28]([O-:33])(=[O:32])[C:29]([O-:31])=[O:30].[CH2:5]([P+:7]([C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1)([C:8]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1)[C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1)[CH3:6].[CH2:5]([P+:7]([C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1)([C:8]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1)[C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1)[CH3:6]