Ammonium → HCID 178527409, compound

HRID 1169544Notes

Reaction equation

HRID 1169544 reaction equation
[F-].[K+:2].C1COS(=O)(=O)CC1.[C:11]([O:24][CH2:25][CH2:26][CH2:27][CH2:28][S:29]([OH:32])(=[O:31])=[O:30])([C:14]([C:17]([C:20]([F:23])([F:22])[F:21])([F:19])[F:18])([F:16])[F:15])([F:13])[F:12].[NH4+]>>[C:11]([O:24][CH2:25][CH2:26][CH2:27][CH2:28][S:29]([O:32][K:2])(=[O:31])=[O:30])([C:14]([C:17]([C:20]([F:23])([F:21])[F:22])([F:19])[F:18])([F:16])[F:15])([F:13])[F:12]

Participants

5

Reactant 4

HCID 223AmmoniumHCID 154111,4-Butane sultoneHCID 522689Potassium FluorideHCID 858794294-(1,1,2,2,3,3,4,4,4-Nonafluorobutoxy)-1-butanesulfonic acid

Product 1

HCID 178527409HCID 178527409, compound

Procedure

n-C4F9OC4H8SO3K was prepared from normal-perfluorobutyl acid fluoride, KF and 1,4-butane sultone and isolated in 92% purity as described in U.S. Pat. No. 6,890,452, as FC-11. The sulfonic acid salt was converted to the corresponding acid through an ion-exchange column packaged with acidified Amberlite IR-120 ion-exchange resin. The corresponding ammonium salt was prepared by adjusting the pH of C4F9O(CH2)4SO3H aqueous solution to ˜10 with 10% aqueous ammonium solution.

Workup

  1. customisolated in 92% purity

Sources & evidence

ORD record
ord-206ff77da73d4f0baa4dc2a2aab35b03
Source dataset
uspto-grants-2010_11
Patent number
US07824755B2

Reaction notes

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