m-Chloroperbenzoic acid → 2-Benzenesulfinyl-6-bromo-pyridine

HRID 1183476Notes

Reaction equation

HRID 1183476 reaction equation
[Br:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([S:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[N:3]=1.ClC1C=CC=C(C(OO)=[O:23])C=1>C(Cl)Cl>[C:9]1([S:8]([C:4]2[CH:5]=[CH:6][CH:7]=[C:2]([Br:1])[N:3]=2)=[O:23])[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=1

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 8245912-Bromo-6-phenylsulfanylpyridine

Product 1

HCID 866790952-Benzenesulfinyl-6-bromo-pyridine

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

2-Bromo-6-phenylsulfanyl-pyridine (0.5323 g, 2 mmol) was dissolved in CH2Cl2 (20 mL) and m-chloroperbenzoic acid (0.345 g, 2 mmol) was added. The reaction was stirred at room temperature overnight then submitted to aqueous workup and purification on silica gel to give the title compound.

Workup

  1. customthen submitted to aqueous workup and purification on silica gel

Sources & evidence

ORD record
ord-26914c45d55841a4a736b549738cd277
Source dataset
uspto-grants-2014_03
Patent number
US08664220B2

Reaction notes

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