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HRID1186660

反应详情

EQUATION

反应方程式

HRID 1186660 的结构方程式

REACTANTS

反应物

4
结构：CCOC(C)=O
HCID8857

Ethyl acetate

C4H8O2

结构：NS(=O)(=O)c1ccc([N+](=O)[O-])cc1
HCID22784

Benzenesulfonamide, 4-nitro-

C6H6N2O4S

结构：O=C1C(Cl)=C/C(=N\S(=O)(=O)c2cccs2)c2ccccc21
HCID22524852

未命名化合物

结构：CCOC(=O)CSC1=C/C(=N\S(=O)(=O)c2cccs2)c2ccccc2C1=O
HCID58398202

未命名化合物

PRODUCTS

生成物

1
结构：CCOC(=O)CSc1cc(NS(=O)(=O)c2ccc([N+](=O)[O-])cc2)c2ccccc2c1O
HCID44608988

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：ClCCCl
溶剂HCID11

1,2-Dichloroethane

C2H4Cl2

PROCEDURE

实验过程

5.2.25 Ethyl 2-(1-hydroxy-4-(4-nitrophenylsulfonamido)naphthalen-2-ylthio)acetate (9e) was prepared according to the procedure for 8a except using 4-nitrobenzenesulfonamide, 1,2-dichloroethane as solvent and applying 100° C. to the reaction. The reaction was worked up according to the procedure for 12a and the title compound was isolated from the product mixture by flash chromatography (EtOAc/Hex) affording 48 mg (10.4%) as a brown solid, m.p.: 143-145° C.

WORKUP

后处理

  1. customapplying 100° C. to the reaction