Tributyl Phosphate → Tbpa aeea

HRID 1190788Notes

Reaction equation

HRID 1190788 reaction equation
[CH3:1][CH2:2][CH2:3][CH2:4][O:5][P:6]([O:13][CH2:14][CH2:15][CH2:16][CH3:17])([O:8][CH2:9][CH2:10][CH2:11][CH3:12])=[O:7].[CH2:18]([NH2:28])[CH2:19][O:20][CH2:21][CH2:22][O:23][CH2:24][C:25]([OH:27])=[O:26]>>[CH3:12][CH2:11][CH2:10][CH2:9][O:8][P:6]([O:5][CH2:4][CH2:3][CH2:2][CH3:1])([O:13][CH2:14][CH2:15][CH2:16][CH3:17])=[O:7].[CH2:18]([NH2:28])[CH2:19][O:20][CH2:21][CH2:22][O:23][CH2:24][C:25]([OH:27])=[O:26]

Participants

3

Reactant 2

HCID 31357Tributyl PhosphateHCID 362706(2-(2-Aminoethoxy)ethoxy)acetic acid

Product 1

HCID 131731252Tbpa aeea

Procedure

Reaction of TBPA with AEEA gives an TBPA/AEEA adduct. AEEA is sold in commerce by Dow Chemical. 43.6 mmol of TBPA was added to a round bottom flask with 51.00 grams of pure toluene. The mixture is heated to reflux after which 43.6 mmol of AEEA was added dropwise and the solution refluxed for one hour. The toluene is removed using a rotary evaporator to produce a yellow solid.

Sources & evidence

ORD record
ord-580b6dff96b84b95b49292334f0d0c27
Source dataset
uspto-grants-2014_03
Patent number
US08679990B2

Reaction notes

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