Dodecylamine → HCID 86676425, compound

HRID 1192281Notes

Reaction equation

HRID 1192281 reaction equation
[CH2:1]([NH:15][C:16](=[O:22])[C:17]([O:19]CC)=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][NH:7][C:8](=[O:14])[C:9]([O:11]CC)=O.[CH2:23]([NH2:35])[CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34]>C(Cl)(Cl)Cl>[CH2:6]([NH:7][C:8](=[O:14])[C:9]([NH:35][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])=[O:11])[CH2:5][CH2:4][CH2:3][CH2:2][CH2:1][NH:15][C:16](=[O:22])[C:17]([NH:35][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])=[O:19]

Participants

4

Reactant 2

HCID 13583DodecylamineHCID 86676426HCID 86676426, compound

Product 1

HCID 86676425HCID 86676425, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

Diethyl 2,2′-(hexane-1,6-diylbis(azanediyl))bis(2-oxoacetate) (5.00 g, 15.8 mmol) and dodecyl amine (5.85 g, 31.64 mmol) were dissolved in 100 ml of CHCl3. Subsequently the mixture was heated at reflux temperature for 24 hours. The solvent was removed by filtering the product. The remaining solid was washed two times with CHCl3 and two times with diethyl ether and dried in vacuum. The product was obtained as a white powder.

Workup

  1. temperatureSubsequently the mixture was heated
  2. temperatureat reflux temperature for 24 hours
  3. customThe solvent was removed
  4. filtrationby filtering the product
  5. washThe remaining solid was washed two times with CHCl3 and two times with diethyl ether
  6. customdried in vacuum
  7. customThe product was obtained as a white powder

Sources & evidence

ORD record
ord-357181fd72e34adbb817e404899fdfb8
Source dataset
uspto-grants-2014_03
Patent number
US08680186B2

Reaction notes

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