5-Vinyl-2-norbornene → HCID 3353303, compound

HRID 1194515Notes

Reaction equation

HRID 1194515 reaction equation
[CH:1]([CH:3]1[CH2:8][CH:7]2[CH2:9][CH:4]1[CH:5]=[CH:6]2)=[CH2:2].[CH3:10][SiH:11]([CH3:13])[Cl:12]>C(O)(C)C.[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl>[CH:7]12[CH2:9][CH:4]([CH:3]([CH2:1][CH2:2][Si:11]([CH3:13])([CH3:10])[Cl:12])[CH2:8]1)[CH:5]=[CH:6]2

Participants

5

Reactant 2

HCID 182735-Vinyl-2-norborneneHCID 66108Chlorodimethylsilane

Product 1

HCID 3353303HCID 3353303, compound

Reagents, catalysts & solvents 2

HCID 61859Chloroplatinic acidCatalystHCID 3776IsopropanolSolvent

Conditions

Temperature
70 °C

Procedure

To a flask equipped with a dropping funnel were charged 150 parts of 2-vinyl-5-norbornene and 0.1 part of a solution of chloroplatinic acid in isopropanol (containing 2% as a platinum atom) were charged. While heating to 70° C., 136 parts of dimethylchlorosilane were added dropwise to the mixture and reacted at 70° C. for an hour. Distillation was performed under reduced pressure to give 195 parts of 2-(5-norbornenyl)ethyldimethylchlorosilane.

Workup

  1. customTo a flask equipped with a dropping funnel
  2. additioncontaining 2% as a platinum atom)
  3. additionwere charged
  4. customreacted at 70° C. for an hour
  5. distillationDistillation

Sources & evidence

ORD record
ord-566b944aae7e4fa4998ebff918d81d3b
Source dataset
uspto-grants-1989_03
Patent number
US04814475

Reaction notes

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