Bromide ion → Ethane, 2-bromo-1,1-diethoxy-

HRID 1196749Notes

Reaction equation

HRID 1196749 reaction equation
[C:1]([O:4][CH:5]=[CH2:6])(=[O:3])[CH3:2].C(Cl)(Cl)(Cl)Cl.[Br-:12].[CH2:13](O)[CH3:14]>>[CH2:5]([O:4][CH:1]([O:3][CH2:13][CH3:14])[CH2:2][Br:12])[CH3:6]

Participants

5

Reactant 4

HCID 259Bromide ionHCID 702EthanolHCID 5943Carbon Tetrachloride2×HCID 7904Vinyl Acetate

Product 1

HCID 74852Ethane, 2-bromo-1,1-diethoxy-

Procedure

To a mixture of 10 g of vinyl acetate and 20 ml of carbon tetrachloride under cooling (temperature 10° C.) 10 ml of carbon tetrachloride and 18.5 g of bromide solution are added. 60 ml of ethanol are added to the mixture and it remains standing for 2 days. The organic phase is washed twice with 50 ml of water, then it is distilled in vacuo.

Workup

  1. additionare added
  2. washThe organic phase is washed twice with 50 ml of water
  3. distillationit is distilled in vacuo

Sources & evidence

ORD record
ord-9ca5f762897d4da08106cabf3f5d88ce
Source dataset
uspto-grants-1992_05
Patent number
US05116402

Reaction notes

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