huagongshe.com
HRID1198050

反应详情

EQUATION

反应方程式

HRID 1198050 的结构方程式

REACTANTS

反应物

3
结构：CCCCCCCCCCCCCC(C)=O
HCID61303

2-Pentadecanone

C15H30O

结构：CC(C)c1cccc(C(C)C)c1N=C=O
HCID92259

2,6-Diisopropylphenyl isocyanate

C13H17NO

结构：CC(C)[N-]C(C)C.[Li+]
HCID2724682

2-Propanamine, N-(1-methylethyl)-, lithium salt

C6H14LiN

PRODUCTS

生成物

1
结构：CCCCCCCCCCCCCC(=O)CC(=O)Nc1c(C(C)C)cccc1C(C)C
HCID9980090

未命名化合物

PROCEDURE

实验过程

The title compound was prepared from 2-pentadecanone (3.0 g, 0.013 mol), 2,6-diisopropylphenyl isocyanate (2.64 g, 0.013 mol), and lithium diisopropylamide (0.013 mol) using the procedure described in Example 1. Purification by flash chromatography (silica gel, 15% EtOAc/hexane) yielded 1.92 g (0.004, 34%) of the desired product.

WORKUP

后处理

  1. customPurification by flash chromatography (silica gel, 15% EtOAc/hexane)