2-Undecanone → HCID 10317246, compound

HRID 1198051Notes

Reaction equation

HRID 1198051 reaction equation
[CH3:1][C:2](=[O:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[CH:13]([C:16]1[CH:21]=[CH:20][CH:19]=[C:18]([CH:22]([CH3:24])[CH3:23])[C:17]=1[N:25]=[C:26]=[O:27])([CH3:15])[CH3:14].C([N-]C(C)C)(C)C.[Li+]>>[CH3:15][CH:13]([C:16]1[CH:21]=[CH:20][CH:19]=[C:18]([CH:22]([CH3:23])[CH3:24])[C:17]=1[NH:25][C:26](=[O:27])[CH2:1][C:2](=[O:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH3:14]

Participants

4

Reactant 3

HCID 81632-UndecanoneHCID 922592,6-Diisopropylphenyl isocyanateHCID 2724682Lithium diisopropylamide

Product 1

HCID 10317246HCID 10317246, compound

Procedure

The title compound was prepared from 2-undecanone (5.0 g, 0.029 mol), 2,6-diisopropylphenyl isocyanate (5.96 g, 0.029 mol), and lithium diisopropylamide (0.029 mol) using the procedure described in Example 1. The desired product was obtained in 79.4% yield (8.6 g, 0.023 mol).

Sources & evidence

ORD record
ord-ed253bd5f3074f5aa0a569a2b6e40ec6
Source dataset
uspto-grants-1994_01
Patent number
US05278326

Reaction notes

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