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HRID1198213

反应详情

EQUATION

反应方程式

HRID 1198213 的结构方程式

REACTANTS

反应物

2
结构：CCOC(=O)CC(C)=O
HCID8868

Ethyl acetoacetate

C6H10O3

结构：CCCCCCc1ccc(C=O)cc1
HCID170813

Benzaldehyde, 4-hexyl-

C13H18O

PRODUCTS

生成物

1
结构：CCCCCCc1ccc(/C=C(/C(C)=O)C(=O)OCC)cc1
HCID67820812

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：C1CCNCC1
催化剂HCID8082

Piperidine

C5H11N

CONDITIONS

反应条件

温度
70 °C

PROCEDURE

实验过程

Ethyl acetoacetate (3.9g, 0.03 moles), parahexylbenzaldehyde (3.8g, 0.02 moles) and piperidine (3 drops) were stirred at room temperature for 20 hrs. and then stirred for 4 days at 70° C. Products A and B were separated and purified by silica gel chromatography. Structure assignments were supported by NMR, infrared and uv spectra and elemental analysis (302.4).

WORKUP

后处理

  1. customProducts A and B were separated
  2. custompurified by silica gel chromatography