HCID 123850930, compound → HCID 19103285, compound
Reaction equation
[CH3:1][SiH:2]([CH3:10])[N:3]([CH2:7][CH:8]=[CH2:9])[CH2:4][CH:5]=[CH2:6]>[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl.C1C=CC=CC=1>[CH2:4]([N:3]1[CH2:7][CH:8]([CH3:9])[Si:2]1([CH3:10])[CH3:1])[CH:5]=[CH2:6].[CH2:4]([N:3]1[CH2:7][CH2:8][CH2:9][Si:2]1([CH3:10])[CH3:1])[CH:5]=[CH2:6]Participants
5
Reactant 1
Product 2
Reagents, catalysts & solvents 2
Conditions
- Temperature
- 80 °C
Procedure
Comparison Example 2. Into a glass tube with an outside diameter of 10 mm and a length of 10 cm were introduced 0.002 mL of a 20 weight % isopropanolic chloroplatinic acid solution and 2 mL of a mixture of 1 part N-dimethylsilyldiallylamine and 3 parts benzene, and the tube was sealed. The tube was heated for 17 hours at 80° C. The conversion of starting material was 100 weight %. 1-Allyl-2,2,3-trimethyl-1-aza-2-silacyclobutane and 1-allyl-2,2-dimethyl-1-aza -2-silacyclopentane were produced in a molar ratio of 66:34 and a combined yield of 55%.
Workup
- customthe tube was sealed
Sources & evidence
- ORD record
- ord-43844141b8d64791aaa41211e6bd08ec
- Source dataset
- uspto-grants-1994_01
- Patent number
- US05281736
Reaction notes
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