Hydrogen Peroxide → HCID 14835365, compound

HRID 1198998Notes

Reaction equation

HRID 1198998 reaction equation
OO.[NH2:3][C:4]1[C:9]([CH3:10])=[CH:8][CH:7]=[CH:6][C:5]=1[C:11]([C:13]1[CH:18]=[CH:17][C:16]([Br:19])=[CH:15][CH:14]=1)=[O:12]>C(O)(=O)C>[Br:19][C:16]1[CH:17]=[CH:18][C:13]([C:11]2[O:12][N:3]=[C:4]3[C:9]([CH3:10])=[CH:8][CH:7]=[CH:6][C:5]=23)=[CH:14][CH:15]=1

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 14835364Methanone, (2-amino-3-methylphenyl)(4-bromophenyl)-

Product 1

HCID 14835365HCID 14835365, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent2×

Conditions

Temperature
95 °C

Procedure

A solution of 130 ml of 30% hydrogen peroxide in 350 ml of glacial acetic acid was heated on a steam bath for 1 hr. To the cooled solution was added a solution of 31.0 g (0.11 mole) of (2-amino-3-methylphenyl)(4-bromophenyl)methanone in 400 ml of glacial acetic acid. The reaction mixture was heated to 95° C. to dissolve all solids, then heated at 65°-70° C. for 4 hr and let stand at ambient temperature overnight.

Workup

  1. dissolutionto dissolve all solids
  2. temperatureheated at 65°-70° C. for 4 hr

Sources & evidence

ORD record
ord-15b894f650d341b4ab94186090b96d09
Source dataset
uspto-grants-1990_02
Patent number
US04898874

Reaction notes

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