Perchloric Acid → HCID 19864935, compound

HRID 1200286Notes

Reaction equation

HRID 1200286 reaction equation
[CH3:1][O:2][C:3]([CH2:5][CH2:6][CH2:7][C:8]([C:11]1[CH:16]=[CH:15][C:14]([OH:17])=[CH:13][CH:12]=1)([CH3:10])[CH3:9])=[O:4].[CH2:18]([O:22][CH2:23][CH2:24][CH:25]([CH2:27][CH2:28][CH:29]=[C:30]([CH3:32])[CH3:31])[CH3:26])[CH2:19][CH2:20][CH3:21].Cl(O)(=O)(=O)=O>C(Cl)Cl>[CH2:18]([O:22][CH2:23][CH2:24][CH:25]([CH3:26])[CH2:27][CH2:28][CH2:29][C:30]([C:15]1[CH:16]=[C:11]([C:8]([CH3:10])([CH2:7][CH2:6][CH2:5][C:3]([O:2][CH3:1])=[O:4])[CH3:9])[CH:12]=[CH:13][C:14]=1[OH:17])([CH3:32])[CH3:31])[CH2:19][CH2:20][CH3:21]

Participants

5

Reactant 3

HCID 24247Perchloric AcidHCID 1167352-Octene, 8-butoxy-2,6-dimethyl-HCID 19865004HCID 19865004, compound

Product 1

HCID 19864935HCID 19864935, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

10.3 Parts of 4-(5-methoxycarbonyl-2-methyl-pent-2-yl)-phenol, 4.2 parts of citronellyl n-butyl ether, and 0.5 parts of 70% perchloric acid in 25 parts of methylene chloride were stored at room temperature for 4 days. The work-up followed Example 61 and gave on distillation 2-(8-n-butyloxy-2,6-dimethyl-oct-2-yl)-4-(5-methoxycarbonyl-2-methyl-pent-2-yl)-phenol with b0.8, 228°-36° C.

Sources & evidence

ORD record
ord-664e152e28794d879218371f1174bf46
Source dataset
uspto-grants-1990_02
Patent number
US04904815

Reaction notes

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