Perchloric Acid → HCID 19865037, compound

HRID 1200287Notes

Reaction equation

HRID 1200287 reaction equation
[CH2:1]([C:11]1[CH:16]=[CH:15][C:14]([OH:17])=[CH:13][CH:12]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[CH3:18][C:19](=[CH2:27])[CH2:20][CH2:21][CH2:22][C:23]([O:25][CH3:26])=[O:24].Cl(O)(=O)(=O)=O>C(Cl)Cl>[CH2:1]([C:11]1[CH:16]=[CH:15][C:14]([OH:17])=[C:13]([C:19]([CH3:27])([CH3:18])[CH2:20][CH2:21][CH2:22][C:23]([O:25][CH3:26])=[O:24])[CH:12]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]

Participants

5

Reactant 3

HCID 24247Perchloric AcidHCID 572479Phenol, p-decyl-HCID 642298methyl 5-methylhex-5-enoate

Product 1

HCID 19865037HCID 19865037, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

2.3 Parts of 4-n-decylphenol, 1.4 parts of methyl 5-methyl-hex-5-enoate, 0.25 of 70% perchloric acid, and 10 parts of methylene chloride were stored for 12 days at room temperature. The work up followed Example 61 and gave on distillation, methyl 5-(5-n-decyl-2-hydroxyphenyl)-5-methyl-hexanoate, b0.8, 160°-7° C.

Sources & evidence

ORD record
ord-2cff0c88e9064de3986b1b02394e1129
Source dataset
uspto-grants-1990_02
Patent number
US04904815

Reaction notes

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