Acetate → 2-(2-Bromophenyl)pyridine

HRID 1200385Notes

Reaction equation

HRID 1200385 reaction equation
[Br:1][c:2]1[cH:3][cH:4][cH:5][cH:6][n:7]1.[Br:8][c:9]1[c:10]([B:15]([OH:16])[OH:17])[cH:11][cH:12][cH:13][cH:14]1.[CH3:52][O:53][CH2:54][CH2:55][O:56][CH3:57].[K+:37].[K+:38].[O-:39][C:40]([O-:41])=[O:42].[O-:44][C:45]([CH3:46])=[O:47].[O-:48][C:49]([CH3:50])=[O:51].[Pd+2:43].[c:18]1([P:19]([c:20]2[cH:21][cH:22][cH:23][cH:24][cH:25]2)[c:26]2[cH:27][cH:28][cH:29][cH:30][cH:31]2)[cH:32][cH:33][cH:34][cH:35][cH:36]1>>[c:2]1(-[c:10]2[c:9]([Br:8])[cH:14][cH:13][cH:12][cH:11]2)[cH:3][cH:4][cH:5][cH:6][n:7]1

Participants

9

Reactant 8

HCID 175Acetate2×HCID 813Potassium Cation2×HCID 79732-BromopyridineHCID 80711,2-DimethoxyethaneHCID 11776TriphenylphosphineHCID 19660Carbonate IonHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 2773294(2-Bromophenyl)boronic acid

Product 1

HCID 132239292-(2-Bromophenyl)pyridine

Sources & evidence

ORD record
ord-ab7defea619f48159111cd1b41c34d6d
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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