Potassium Cation → (+/-)-2a,6-Dimethyl-1,2,2a,5-tetrahydropyrrolo[4,3,2-de]quinolin-4(3H)-one
Reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]2[c:6]3[c:11]1[NH:10][C:9](=[O:12])[CH2:8][C:7]3([CH3:15])[CH2:13][NH:14]2.[C:16](=[O:17])([O-:18])[O-:19].[CH2:32]1[O:33][CH2:34][CH2:35][CH2:36]1.[CH2:37]1[O:38][CH2:39][CH2:40][O:41][CH2:42]1.[CH3:22][B:23]1[O:24][B:25]([CH3:26])[O:27][B:28]([CH3:29])[O:30]1.[K+:20].[K+:21].[OH2:31].[cH:43]1[cH:44][cH:45][c:46]([P:47]([Pd:48]([P:49]([c:50]2[cH:51][cH:52][cH:53][cH:54][cH:55]2)([c:56]2[cH:57][cH:58][cH:59][cH:60][cH:61]2)[c:62]2[cH:63][cH:64][cH:65][cH:66][cH:67]2)([P:68]([c:69]2[cH:70][cH:71][cH:72][cH:73][cH:74]2)([c:75]2[cH:76][cH:77][cH:78][cH:79][cH:80]2)[c:81]2[cH:82][cH:83][cH:84][cH:85][cH:86]2)[P:87]([c:88]2[cH:89][cH:90][cH:91][cH:92][cH:93]2)([c:94]2[cH:95][cH:96][cH:97][cH:98][cH:99]2)[c:100]2[cH:101][cH:102][cH:103][cH:104][cH:105]2)([c:106]2[cH:107][cH:108][cH:109][cH:110][cH:111]2)[c:112]2[cH:113][cH:114][cH:115][cH:116][cH:117]2)[cH:118][cH:119]1>>[c:2]1([CH3:16])[cH:3][cH:4][c:5]2[c:6]3[c:11]1[NH:10][C:9](=[O:12])[CH2:8][C:7]3([CH3:15])[CH2:13][NH:14]2Participants
9
Reactant 8
Product 1
Sources & evidence
- ORD record
- ord-9f2215e101954fdaa1d8daf2af92845b
- Source dataset
- Training data from https://doi.org/10.1039/C8SC04228D (5/10)
Reaction notes
Loading…