(+-)-Methionine → benzyl N-(3-bromo-7-oxo-1,2,5,6-tetrahydroazepin-6-yl)carbamate

HRID 1207565Notes

Reaction equation

HRID 1207565 reaction equation
[Br:10][C:11]1=[CH:12][CH2:13][CH:14]([NH:30][C:31]([O:32][CH2:33][c:34]2[cH:35][cH:36][cH:37][cH:38][cH:39]2)=[O:40])[C:15](=[O:29])[N:16]([CH2:18][c:19]2[cH:20][cH:21][c:22]([O:23][CH3:24])[cH:25][c:26]2[O:27][CH3:28])[CH2:17]1.[CH3:1][S:2][CH2:3][CH2:4][CH:5]([C:6](=[O:7])[OH:8])[NH2:9].[Cl:48][CH2:49][Cl:50].[OH:41][C:42]([C:43]([F:44])([F:45])[F:46])=[O:47]>>[Br:10][C:11]1=[CH:12][CH2:13][CH:14]([NH:30][C:31]([O:32][CH2:33][c:34]2[cH:35][cH:36][cH:37][cH:38][cH:39]2)=[O:40])[C:15](=[O:29])[NH:16][CH2:17]1

Participants

5

Reactant 4

HCID 876(+-)-MethionineHCID 6344DichloromethaneHCID 6422Trifluoroacetic acidHCID 23395535HCID 23395535, compound

Product 1

HCID 23395536benzyl N-(3-bromo-7-oxo-1,2,5,6-tetrahydroazepin-6-yl)carbamate

Sources & evidence

ORD record
ord-c896e80cc9d943e99329f0b3cde080c7
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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