Sodium ion → 6-bromo-1-(triisopropylsilyl)-1H-indole

HRID 1211028Notes

Reaction equation

HRID 1211028 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]2[cH:6][cH:7][nH:8][c:9]2[cH:10]1.[CH:13]([CH3:14])([CH3:15])[Si:16]([CH:17]([CH3:18])[CH3:19])([CH:20]([CH3:21])[CH3:22])[Cl:23].[H-:12].[Na+:11].[O:24]=[CH:25][N:26]([CH3:27])[CH3:28]>>[Br:1][c:2]1[cH:3][cH:4][c:5]2[cH:6][cH:7][n:8]([Si:16]([CH:13]([CH3:14])[CH3:15])([CH:17]([CH3:18])[CH3:19])[CH:20]([CH3:21])[CH3:22])[c:9]2[cH:10]1

Participants

6

Reactant 5

HCID 923Sodium ionHCID 6228DimethylformamideHCID 139400Triisopropylsilyl chlorideHCID 166653HydrideHCID 6764936-Bromoindole

Product 1

HCID 129912436-bromo-1-(triisopropylsilyl)-1H-indole

Sources & evidence

ORD record
ord-48ef03ba2d0742f3a29941d8cbf4d696
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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