Acetate → 2,6-Diformyl-4-(dodecen-1-yl)phenol

HRID 1211715Notes

Reaction equation

HRID 1211715 reaction equation
[Br-:32].[C:50]([O-:51])(=[O:52])[CH3:53].[C:54]([O-:55])(=[O:56])[CH3:57].[CH2:13]=[CH:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24].[CH3:33][CH2:34][CH2:35][CH2:36][N+:37]([CH2:38][CH2:39][CH2:40][CH3:41])([CH2:42][CH2:43][CH2:44][CH3:45])[CH2:46][CH2:47][CH2:48][CH3:49].[CH:1](=[O:2])[c:3]1[c:4]([OH:12])[c:5]([CH:10]=[O:11])[cH:6][c:7]([Br:9])[cH:8]1.[Cl-:30].[Li+:31].[Na+:29].[O-:25][C:26]([OH:27])=[O:28].[Pd+2:58]>>[CH:1](=[O:2])[c:3]1[c:4]([OH:12])[c:5]([CH:10]=[O:11])[cH:6][c:7]([CH:13]=[CH:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[cH:8]1

Participants

11

Reactant 10

HCID 175Acetate2×HCID 259Bromide ionHCID 312ChlorideHCID 769Bicarbonate IonHCID 923Sodium ionHCID 81831-DodeceneHCID 16028TetrabutylammoniumHCID 28486Lithium ionHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 52602065-Bromo-2-hydroxybenzene-1,3-dicarbaldehyde

Product 1

HCID 858556222,6-Diformyl-4-(dodecen-1-yl)phenol

Sources & evidence

ORD record
ord-f020450e673f4102be2c6b9526e0fc63
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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