Sodium ion → Tert-butyl 3,4-diazidopiperidine-1-carboxylate

HRID 1212815Notes

Reaction equation

HRID 1212815 reaction equation
[CH3:26][N:27]([CH3:28])[CH:29]=[O:30].[N-:2]=[N+:3]=[N-:4].[N:5](=[N+:6]=[N-:7])[CH:8]1[CH:9]([O:21][S:22]([CH3:23])(=[O:24])=[O:25])[CH2:10][N:11]([C:14](=[O:15])[O:16][C:17]([CH3:18])([CH3:19])[CH3:20])[CH2:12][CH2:13]1.[Na+:1]>>[N:2](=[N+:3]=[N-:4])[CH:9]1[CH:8]([N:5]=[N+:6]=[N-:7])[CH2:13][CH2:12][N:11]([C:14](=[O:15])[O:16][C:17]([CH3:18])([CH3:19])[CH3:20])[CH2:10]1

Participants

5

Reactant 4

HCID 923Sodium ionHCID 6228DimethylformamideHCID 33558AzideHCID 90857051Tert-butyl 4-azido-3-methylsulfonyloxypiperidine-1-carboxylate

Product 1

HCID 76541415Tert-butyl 3,4-diazidopiperidine-1-carboxylate

Sources & evidence

ORD record
ord-93d29bf1a03043a9b60e75a55ea1571b
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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