HRID1217351

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID679

Dimethyl sulfoxide

C2H6OS

HCID923

Sodium ion

Na+

HCID33558

Azide

N3-

HCID81531

Diisopropylethylamine

C8H19N

结构：CC(OS(C)(=O)=O)c1cc(N(COCC[Si](C)(C)C)COCC[Si](C)(C)C)n2ncc(-c3cnc4ccc(F)cc4c3)c2n1

HCID86664795

未命名化合物

PRODUCTS

生成物

结构：CC(N=[N+]=[N-])c1cc(N(COCC[Si](C)(C)C)COCC[Si](C)(C)C)n2ncc(-c3cnc4ccc(F)cc4c3)c2n1

HCID86664796

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-b3496c336bc14ca8b9d51ed932a8948b
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (5/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (5/10)

反应 SMILES

[CH3:1][S:2]([O:3][CH:6]([CH3:7])[c:8]1[n:9][c:10]2[n:11]([c:12]([N:14]([CH2:15][O:16][CH2:17][CH2:18][Si:19]([CH3:20])([CH3:21])[CH3:22])[CH2:23][O:24][CH2:25][CH2:26][Si:27]([CH3:28])([CH3:29])[CH3:30])[cH:13]1)[n:31][cH:32][c:33]2-[c:34]1[cH:35][n:36][c:37]2[cH:38][cH:39][c:40]([F:44])[cH:41][c:42]2[cH:43]1)(=[O:4])=[O:5].[CH3:58][S:59]([CH3:60])=[O:61].[CH:45]([N:46]([CH2:47][CH3:48])[CH:49]([CH3:50])[CH3:51])([CH3:52])[CH3:53].[N-:55]=[N+:56]=[N-:57].[Na+:54]>>[CH:6]([CH3:7])([c:8]1[n:9][c:10]2[n:11]([c:12]([N:14]([CH2:15][O:16][CH2:17][CH2:18][Si:19]([CH3:20])([CH3:21])[CH3:22])[CH2:23][O:24][CH2:25][CH2:26][Si:27]([CH3:28])([CH3:29])[CH3:30])[cH:13]1)[n:31][cH:32][c:33]2-[c:34]1[cH:35][n:36][c:37]2[cH:38][cH:39][c:40]([F:44])[cH:41][c:42]2[cH:43]1)[N:55]=[N+:56]=[N-:57]