Acetate → 6-O-Acetyl-234-tri-O-benzyl-D-glucopyranose

HRID 1223825Notes

Reaction equation

HRID 1223825 reaction equation
[C:1](=[O:2])([CH3:3])[O:4][CH:5]1[CH:6]([O:7][CH2:8][c:9]2[cH:10][cH:11][cH:12][cH:13][cH:14]2)[CH:15]([O:16][CH2:17][c:18]2[cH:19][cH:20][cH:21][cH:22][cH:23]2)[CH:24]([O:25][CH2:26][c:27]2[cH:28][cH:29][cH:30][cH:31][cH:32]2)[CH:33]([CH2:35][O:36][C:37]([CH3:38])=[O:39])[O:34]1.[C:40]([O-:41])(=[O:42])[CH3:43].[CH3:46][CH2:47][O:48][C:49](=[O:50])[CH3:51].[CH3:53][N:54]([CH3:55])[CH:56]=[O:57].[NH3+:44][NH2:45].[OH2:52]>>[OH:4][CH:5]1[CH:6]([O:7][CH2:8][c:9]2[cH:10][cH:11][cH:12][cH:13][cH:14]2)[CH:15]([O:16][CH2:17][c:18]2[cH:19][cH:20][cH:21][cH:22][cH:23]2)[CH:24]([O:25][CH2:26][c:27]2[cH:28][cH:29][cH:30][cH:31][cH:32]2)[CH:33]([CH2:35][O:36][C:37]([CH3:38])=[O:39])[O:34]1

Participants

7

Reactant 6

HCID 175AcetateHCID 962WaterHCID 6228DimethylformamideHCID 8857Ethyl AcetateHCID 87681Hydrazinium(1+)HCID 4361604((2R,3R,4S,5S,6R)-6-Acetoxy-3,4,5-tris(benzyloxy)-tetrahydro-2H-pyran-2-yl)methyl acetate

Product 1

HCID 145049606-O-Acetyl-234-tri-O-benzyl-D-glucopyranose

Sources & evidence

ORD record
ord-91063aceb0be4c0b88c688032c582783
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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