Dichloromethane → Methyl 5-bromo-6-chloropicolinate

HRID 1223971Notes

Reaction equation

HRID 1223971 reaction equation
[Br:23][c:24]1[cH:25][cH:26][c:27]([C:28]([O:29][CH3:30])=[O:31])[n+:32]([O-:33])[cH:34]1.[CH2:40]([Cl:41])[Cl:42].[CH3:1][O:2][C:3](=[O:4])[c:5]1[n:6][cH:7][c:8]([Br:11])[cH:9][cH:10]1.[Cl:35][P:36](=[O:37])([Cl:38])[Cl:39].[OH:12][O:13][C:14]([c:15]1[cH:16][c:17]([Cl:21])[cH:18][cH:19][cH:20]1)=[O:22]>>[CH3:1][O:2][C:3](=[O:4])[c:5]1[n:6][c:7]([Cl:21])[c:8]([Br:11])[cH:9][cH:10]1

Participants

6

Reactant 5

HCID 6344DichloromethaneHCID 24813Phosphorus oxychlorideHCID 70297m-Chloroperbenzoic acidHCID 7016458Methyl 5-bromopyridine-2-carboxylateHCID 684583815-Bromo-2-(methoxycarbonyl)pyridine 1-oxide

Product 1

HCID 46311197Methyl 5-bromo-6-chloropicolinate

Sources & evidence

ORD record
ord-4376341cde7e471b805ab41349afa961
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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