Acetate → 5-(2-methylphenyl)furan-2-carbaldehyde

HRID 1233451Notes

Reaction equation

HRID 1233451 reaction equation
[Br-:25].[Br:1][c:2]1[cH:3][cH:4][c:5]([CH:7]=[O:8])[o:6]1.[C:9](=[O:10])([O-:11])[O-:12].[CH3:15][c:16]1[c:17]([B:22]([OH:23])[OH:24])[cH:18][cH:19][cH:20][cH:21]1.[CH3:26][CH2:27][CH2:28][CH2:29][N+:30]([CH2:31][CH2:32][CH2:33][CH3:34])([CH2:35][CH2:36][CH2:37][CH3:38])[CH2:39][CH2:40][CH2:41][CH3:42].[CH3:44][CH2:45][O:46][C:47](=[O:48])[CH3:49].[K+:13].[K+:14].[O-:51][C:52]([CH3:53])=[O:54].[O-:55][C:56]([CH3:57])=[O:58].[OH2:43].[Pd+2:50]>>[c:2]1(-[c:17]2[c:16]([CH3:15])[cH:21][cH:20][cH:19][cH:18]2)[cH:3][cH:4][c:5]([CH:7]=[O:8])[o:6]1

Participants

11

Reactant 10

HCID 175Acetate2×HCID 259Bromide ionHCID 813Potassium Cation2×HCID 962WaterHCID 8857Ethyl AcetateHCID 16028TetrabutylammoniumHCID 19660Carbonate IonHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 6003285-Bromofuran-2-carbaldehydeHCID 27332672-Methylphenyl boronic acid

Product 1

HCID 46748245-(2-methylphenyl)furan-2-carbaldehyde

Sources & evidence

ORD record
ord-09e888650d8847f7a026615458d3e4a1
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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