Dimethylformamide → 3-(2-Bromo-cyclopent-1-enyl)benzoic Acid Ethyl Ester

HRID 1238180Notes

Reaction equation

HRID 1238180 reaction equation
[Br:1][C:2]1=[C:3]([Sn:7]([CH3:8])([CH3:9])[CH3:10])[CH2:4][CH2:5][CH2:6]1.[CH2:11]([CH3:12])[O:13][C:14]([c:15]1[cH:16][c:17]([I:21])[cH:18][cH:19][cH:20]1)=[O:22].[CH3:42][N:43]([CH3:44])[CH:45]=[O:46].[cH:23]1[cH:24][cH:25][c:26]([As:27]([c:28]2[cH:29][cH:30][cH:31][cH:32][cH:33]2)[c:34]2[cH:35][cH:36][cH:37][cH:38][cH:39]2)[cH:40][cH:41]1>>[Br:1][C:2]1=[C:3]([c:17]2[cH:16][c:15]([C:14]([O:13][CH2:11][CH3:12])=[O:22])[cH:20][cH:19][cH:18]2)[CH2:4][CH2:5][CH2:6]1

Participants

5

Reactant 4

HCID 6228DimethylformamideHCID 11773TriphenylarsineHCID 143542Ethyl 3-iodobenzoateHCID 12586555(2-Bromo-1-cyclopenten-1-yl)trimethylstannane

Product 1

HCID 578620843-(2-Bromo-cyclopent-1-enyl)benzoic Acid Ethyl Ester

Sources & evidence

ORD record
ord-33f5ec00424240b7acdcd3828c5e7339
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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