Acrylic Acid → Tri-isopropyl silyl acrylate

HRID 1244866Notes

Reaction equation

HRID 1244866 reaction equation
[C:1]([O:4][Si:5]([CH:12]([CH3:14])[CH3:13])([CH:9]([CH3:11])[CH3:10])[CH:6]([CH3:8])[CH3:7])(=[O:3])[CH3:2].[C:15](O)(=O)C=C>C1(C)C=CC=CC=1.CN(C)C=O>[C:1]([O:4][Si:5]([CH:9]([CH3:11])[CH3:10])([CH:6]([CH3:8])[CH3:7])[CH:12]([CH3:14])[CH3:13])(=[O:3])[CH:2]=[CH2:15]

Participants

5

Reactant 2

HCID 6581Acrylic AcidHCID 21923867HCID 21923867, compound

Product 1

HCID 167468Tri-isopropyl silyl acrylate

Reagents, catalysts & solvents 2

HCID 1140TolueneSolventHCID 6228DimethylformamideSolvent

Procedure

4 g of acetoxy-triisopropylsilane and 1.6 g of acrylic acid (ATOFINA Norsocryl AA®) in 100 ml of toluene and 1 mL of N,N-dimethylformamide are mixed and heated. Azeotropic distillation of acetic acid affords triisopropylsilyl acrylate.

Workup

  1. temperatureheated
  2. distillationAzeotropic distillation of acetic acid

Sources & evidence

ORD record
ord-1ee8f1dcc122490b89368cae55c6565d
Source dataset
uspto-grants-2006_10
Patent number
US07122692B2

Reaction notes

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