Toluene → HCID 86600217, compound

HRID 1245235Notes

Reaction equation

N[CH2:2][CH2:3][CH2:4][Si:5]([O:10][CH3:11])([O:8][CH3:9])[O:6][CH3:7].C1(C)C=CC=CC=1.[C:19](Cl)(=[O:21])[CH3:20].C([N:25](CC)CC)C>>[CH3:7][O:6][Si:5]([CH2:4][CH2:3][CH2:2][CH2:20][C:19]([NH2:25])=[O:21])([O:10][CH3:11])[O:8][CH3:9]

Participants

Reactant 4

HCID 1140Toluene

HCID 6367Acetyl chloride

HCID 8471Triethylamine

HCID 83756Aminopropyltrimethoxysilane

Product 1

HCID 86600217HCID 86600217, compound

Procedure

A three-neck round-bottomed flask, equipped with a mechanical stirrer, a refluxing condenser and a dropping funnel, was charged with 3-aminopropyltrimethoxysilane (18 gram, Gelest Inc.), toluene (40 mL, Aldrich) and triethylamine (13 gram, Aldrich). Stirring was started, and an appropriate acyl chloride such as acetyl chloride (18 mL, Aldrich) was added dropwise to the flask. The mixture was stirred at room temperature under an argon atmosphere for 16 hours.

Workup

customA three-neck round-bottomed flask, equipped with a mechanical stirrer, a refluxing condenser and a dropping funnel
stirringThe mixture was stirred at room temperature under an argon atmosphere for 16 hours

Sources & evidence

ORD record: ord-3fe0669f389a45cdb4259921cbc4bcd0
Source dataset: uspto-grants-2006_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07125488B2

Reaction notes

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