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HRID1248084

反应详情

EQUATION

反应方程式

HRID 1248084 的结构方程式

REACTANTS

反应物

7
结构：[Cl-].[Na+]
HCID5234

Sodium chloride

ClNa

结构：COC(=O)CC(C)=O
HCID7757

Methyl acetoacetate

C5H8O3

结构：CCCCC(=O)[O-]
HCID114781

Pentanoic acid, ion(1-)

C5H9O2-

结构：[Na]
HCID5360545

Sodium

Na

结构：CC(Oc1ccc(Oc2cnc3cc(Cl)ccc3n2)cc1)C(=O)Cl
HCID13370018

未命名化合物

结构：COC(=O)C(C(C)=O)C(=O)C(C)Oc1ccc(Oc2cnc3cc(Cl)ccc3n2)cc1
HCID20278385

未命名化合物

结构：[H][H]
HCID178418361

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)CC(=O)C(C)Oc1ccc(Oc2cnc3cc(Cl)ccc3n2)cc1
HCID20278374

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CS(C)=O
溶剂HCID679

Dimethyl sulfoxide

C2H6OS

PROCEDURE

实验过程

In the same manner, methyl 2-acetyl-4-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]-3-oxopentanoate (XIV; X' is chloro and X" is hydrogen) is prepared from 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]propionic acid chloride and the sodium salt of methylacetoacetate. This pentanoate is then heated with sodium chloride and DMSO to yield 5-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]-2,4-hexanedione (XV; X' is chloro and X" is hydrogen).