Chlorotriethylsilane → HCID 20223389, compound

HRID 1249477Notes

Reaction equation

HRID 1249477 reaction equation
[CH2:1]([OH:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7]/[CH:8]=[CH:9]/[CH:10]=[CH:11]/[CH3:12].[CH2:14]([Si:16]([CH2:20][CH3:21])([CH2:18][CH3:19])Cl)[CH3:15]>C(N(CC)CC)C>[CH2:1]([O:13][Si:16]([CH2:20][CH3:21])([CH2:18][CH3:19])[CH2:14][CH3:15])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7]/[CH:8]=[CH:9]/[CH:10]=[CH:11]/[CH3:12]

Participants

4

Reactant 2

HCID 13819ChlorotriethylsilaneHCID 1787910(8E,10E)-8,10-Dodecadien-1-ol

Product 1

HCID 20223389HCID 20223389, compound

Reagents, catalysts & solvents 1

HCID 8471TriethylamineSolvent

Procedure

A mixture of trans,trans-8,10-dodecadien-1-ol (1.82 g), triethylamine (3.5 ml) and triethyl-chlorosilane (1.85 ml) is held at 25° C. for 15 hours. After dilution of the mixture with hexane (100 ml), it is thoroughly washed with ice-water (3×50 ml), dried (CaSO4), concentrated by evaporation and distilled. The title compound is obtained in the boiling range of 107° to 112° C. (nD20 =1.4697).

Workup

  1. washAfter dilution of the mixture with hexane (100 ml), it is thoroughly washed with ice-water (3×50 ml)
  2. dry with materialdried (CaSO4)
  3. concentrationconcentrated by evaporation
  4. distillationdistilled

Sources & evidence

ORD record
ord-9c06d6d29f1d49b6b33dd787c1251db9
Source dataset
uspto-grants-1986_12
Patent number
US04632827

Reaction notes

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