Dimethyl Sulfide → HCID 54310765, compound

HRID 1249501Notes

Reaction equation

HRID 1249501 reaction equation
[O:1]1[CH2:5][CH2:4][O:3][CH:2]1[C:6]([C:9]([CH2:11][CH2:12][C:13]1[CH:18]=[CH:17][C:16]([Cl:19])=[CH:15][C:14]=1[Cl:20])=[O:10])([CH3:8])[CH3:7].[CH3:21]SC.CI>>[Cl:20][C:14]1[CH:15]=[C:16]([Cl:19])[CH:17]=[CH:18][C:13]=1[CH2:12][CH2:11][C:9]1([C:6]([CH:2]2[O:3][CH2:4][CH2:5][O:1]2)([CH3:8])[CH3:7])[CH2:21][O:10]1

Participants

4

Reactant 3

HCID 1068Dimethyl SulfideHCID 6328Methyl iodideHCID 13342257HCID 13342257, compound

Product 1

HCID 54310765HCID 54310765, compound

Procedure

In accordance with Example 3, reaction of 83 g (0.262 mol) of b 2,4-dichlorophenylethyl 2-(1,3-dioxolan-2-yl)-prop-2-yl ketone with 28.2 g (0.455 mol) of dimethyl sulphide/60 g of methyl iodide gives 90 g of 2-(2,4-dichlorophenylethyl)-2-[2-(1,3-dioxolan-2-yl)-prop-2-yl]-oxirane as an oil, which is directly reacted further. ##STR103##

Sources & evidence

ORD record
ord-2ef7693c17c547b8b9d9394e220c89e0
Source dataset
uspto-grants-1986_12
Patent number
US04632932

Reaction notes

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