4-Toluenesulfonyl chloride → HCID 14274197, compound

HRID 1252667Notes

Reaction equation

HRID 1252667 reaction equation
[CH2:1]([OH:6])[CH:2](O)[CH2:3][CH3:4].C1(C)C=CC(S(Cl)(=O)=O)=CC=1.[C:18]1([CH3:33])[CH:23]=[CH:22][C:21]([S:24]([O:27][CH2:28][CH:29]([OH:32])[CH2:30][CH3:31])(=[O:26])=[O:25])=[CH:20][CH:19]=1>N1C=CC=CC=1>[C:1]([O:32][CH:29]([CH2:30][CH3:31])[CH2:28][O:27][S:24]([C:21]1[CH:20]=[CH:19][C:18]([CH3:33])=[CH:23][CH:22]=1)(=[O:25])=[O:26])(=[O:6])[CH2:2][CH2:3][CH3:4]

Participants

5

Reactant 3

HCID 73974-Toluenesulfonyl chlorideHCID 114291,2-ButanediolHCID 14153952HCID 14153952, compound

Product 1

HCID 14274197HCID 14274197, compound

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

Using 1,2-butanediol, pyridine and p-toluenesulfonyl chloride, (RS)-1-p-toluenesulfonyloxy-2-butanol 2b ##STR24## was prepared in the same manner as Example 1 of Production.

Workup

  1. customwas prepared in the same manner as Example 1 of Production

Sources & evidence

ORD record
ord-2ee906d9995b43b9b893b338117fb1d3
Source dataset
uspto-grants-1988_05
Patent number
US04745066

Reaction notes

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