Carbon Disulfide → HCID 54538331, compound

HRID 1253235Notes

Reaction equation

HRID 1253235 reaction equation
[NH2:1][C:2]1[O:3][C:4]([CH3:8])=[C:5]([CH3:7])[N:6]=1.[C:9](=[S:11])=[S:10].C(N(CC)CC)C.Br[CH2:20][CH2:21][C:22]([F:26])=[C:23]([F:25])[F:24]>CS(C)=O>[CH3:7][C:5]1[N:6]=[C:2]([NH:1][C:9](=[S:11])[S:10][CH2:20][CH2:21][C:22]([F:26])=[C:23]([F:25])[F:24])[O:3][C:4]=1[CH3:8]

Participants

6

Reactant 4

HCID 6348Carbon DisulfideHCID 8471TriethylamineHCID 663334-Bromo-1,1,2-trifluorobut-1-eneHCID 5358704,5-Dimethyloxazol-2-amine

Product 1

HCID 54538331HCID 54538331, compoundYield 34.7%

Reagents, catalysts & solvents 1

HCID 679Dimethyl SulfoxideSolvent

Procedure

In a manner similar to Example 9, Step (a), 2-amino-4,5-dimethyloxazole (3.0 grams, 0.027 mole), carbon disulfide (2.67 grams, 0.035 mole), triethylamine (3.44 grams, 0.34 mole), dimethyl sulfoxide (13.5 ml) and 4-bromo-1,1,2-trifluoro-1-butene (6.43 grams, 0.034 mole) were reacted to produce 2.78 grams of (3,4,4-trifluoro-3-butenyl) N-(4,5-dimethyl-2-oxazolyl)dithiocarbamate. The NMR spectrum was consistent with the proposed structure.

Sources & evidence

ORD record
ord-cd235d75e5e440ca88643a9253793fbb
Source dataset
uspto-grants-1988_05
Patent number
US04748186

Reaction notes

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