Water → HCID 13073691, compound

HRID 1262785Notes

Reaction equation

HRID 1262785 reaction equation
[Cl:1][C:2]1[CH:7]=[C:6]([N+]([O-])=O)[CH:5]=[C:4]([Cl:11])[N:3]=1.[Cl:12][C:13]1[CH:18]=[C:17]([S:19][CH3:20])[C:16]([Cl:21])=[CH:15][C:14]=1[OH:22].C([O-])([O-])=O.[K+].[K+].O>CC(C)=O>[Cl:1][C:2]1[CH:7]=[C:6]([O:22][C:14]2[CH:15]=[C:16]([Cl:21])[C:17]([S:19][CH3:20])=[CH:18][C:13]=2[Cl:12])[CH:5]=[C:4]([Cl:11])[N:3]=1

Participants

6

Reactant 4

HCID 962WaterHCID 11430Potassium CarbonateHCID 38410702,6-Dichloro-4-nitropyridineHCID 54506707HCID 54506707, compound

Product 1

HCID 13073691HCID 13073691, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

Quantities of 19.3 gm (0.1 mol) of 2,6-dichloro-4-nitropyridine and 23.1 gm (0.11 mol) of 2,5-dichloro-4-methylmercaptophenol were dissolved in 100 ml of acetone, 13.8 gm (0.1 mol) of K2CO3 were added, and the resulting mixture was stirred for 3 hours under reflux. It was then stirred into 500 ml of water, and the precipitate formed was recovered by suction filtration.

Workup

  1. temperatureunder reflux
  2. customthe precipitate formed
  3. filtrationwas recovered by suction filtration

Sources & evidence

ORD record
ord-1feb865e8d6c4138848c6fd5fd34c49c
Source dataset
uspto-grants-1984_06
Patent number
US04453972

Reaction notes

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